CALIFORNIA STATE POLYTECHNIC UNIVERSITY, PONONA – Winter 2009
CHE 303 CHEMICAL ENGINEERING THERMODYNAMICS II*
9AO
TIME: Sec. 2. (MWF 13:00-14:05 (PM)).
ROOM: M(9-277), WF(17-2133)
INSTRUCTOR: Dr. Lloyd L. Lee (Office:: 17-2114 Phone: (909) 869-2423)
Office Hours: MWF 12:00-13:00, F 14:15-16:15.
Class web page www.csupomona.edu/~lllee (under construction)
TEXT:
1. Fundamentals of Engineering Thermodynamics; Moran & Shapiro (Wiley, New York 2008), 6th Ed. (ISBN 13-0471-78735-8).
2. Class handouts
Instructional Objectives
After completing this course, students should be able to do the following:
1. Make calculations for the fugacities and activities for mixtures and pure substances.
2. Determine the phase boundaries for vapor-liquid equilibria.
3. Use activity coefficient models for highly nonideal solutions.
4. Understand and implement phase equilibrium conditions.
5. Learn Gibbs phase rule, Gibbs-Duhem relation, Raoult's law, Henry's law.
6. Apply van Laar, Margules, NRTL, and Wilson methods for activities.
7. Calculate equilibrium compositions for chemical reactions from free energy data.
8. Calculate composition distributions for single and simultaneous chemical reactions.
GRADE:
No late homeworks or reports. No make-up exams.
Quizzes & Attendance 10%
Homework: 20%
Best 2 of 3 Tests (open book & notes) 40%
Comprehensive Final (open book & notes) 30%
WEEK TOPICS READING_____
1 Gas mixtures. Partial molar properties, chemical potential Chap. 11
2 Fugacity. Ideal solutions. y balance. Flame temperature Chap. 11
3 Mixture equations of state. Enthalpy, entropy, & internal energy Chap. 12
4 Mixing rules. Cubic equations of state Class notes
5 Chemical equilibrium. Activities. Equilibrium constant K Chap. 14
6 Reaction composition distributions Chap. 14
7 Competing simultaneous reactions Chap. 14
8 Phase equilibria. Vapor-liquid equilibria Class notes
9 Gibbs phase rule. Activities and activity coefficients Class notes
10 T-x-y, P-x-y diagrams. Equilibrium K-value. Activity models Class notes
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Most homework is done on WileyPlus, unless otherwise specified. No late homework will be accepted.
Academic Integrity
As noted in the University Catalog: "All forms of academic dishonesty at Cal Poly Pomona are a violation of university
policy and will be considered a serious offense." For this course "academic honesty” includes but is not limited to:
“Plagiarism..., Cheating During Exams... and Use of Unauthorized Study Aids..." As a student in this class it is imperative
that you maintain academic integrity and honesty. Cheating can result in a grade of F in this class, or worse! So don't do it.
Tentative Homework and Test Calendar:
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Week Chapter Assignment Test
1 Ch 11 (__)
2 Ch 11 (96,103,105,121,123) Due 1-14 Noon
3 Ch 11 (99,104,124) Due 1-21-09 Noon Test 1
4 Ch 12 (6,10,28,30,38,)
5 Ch 12 (23, 25,26, 27) Test 2
6 Mixing rules (TBA))
7 Ch 14 (25,31,38,41,45)
8 Ch 14 (47,48,49,51,54,56) Test 3
9 Phase equilibria Notes (TBA)
10 Phase equilibria Notes (TBA )
*Schedule subject to change. Watch out for new announcements during the class.
If you need academic accommodations due to physical, psychological or learning disability(ies), please be sure to
contact me as soon as possible so we can discuss what arrangements need to be made.
* Schedule subject to change. Check back the class web often. Watch out for new announcements.